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stituted benzoic acids: the slopes in AN, DMSO and DMF are the same and 2.4 times that in water [8]. The effects of substituents on the pKa of phenols and benzoic acids are much larger in aprotic solvents than in water. The reason for this is that the anions (conjugate bases) of the acids are hydrated in water by hydrogen bonding: in a series of substituted acids, the acids with higher pKa values give anions with higher basicities. Thus, the hydrogen bond between the anions and water is stronger for the acids with higher pKa values. The anions are stabilized by the increased strength of the hydrogen bonding, and the conjugate acids dissociate more easily. Therefore, in water, the hydrogen bonding of water to anions tends to suppress the substituent effect on pKa. In aprotic solvents with poor hydrogen bond donor capacities, such a suppression effect is not observed. This fact is of analytical importance: when two or more acids are to be titrated simultaneously, the resolution is better in aprotic solvents than in water. The resolutions in MeOH and EtOH are between those of water and aprotic solvents. In Table 3.4, the pKa1 and pKa2 values of some diprotic acids are also shown. For sulfuric acid, o-phthalic acid and malonic acid, the values of (pKa2 pKa1) in dipolar aprotic solvents are much higher than those in water. The large (pKa2 pKa1) values are mainly due to the fact that, for those acids in aprotic solvents, monoanions HA are highly stabilized by strong intramolecular hydrogen bonding, while dianions A2 are unstable because two adjacent negative charges, which repel each other, cannot be stabilized by the solvation of aprotic solvents. For dicarboxylic acids, the intramolecular hydrogen bonding of HA is possible only if the

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We selected one major freight forwarder with one backup, explained the international sales manager at an Illinois food services company with 1,700 workers. As a result, we consolidated shipments and utilized contracts, and savings came on commitments. We settled on one forwarder, due to its quick service and ability to handle questions in a timely manner which has resulted in significant savings, said the director of exports at a 100-employee New York firm.

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tmattsson/gs1utils: Utilities for GS1 barcodes - GitHub
Java library for GS1 data structures commonly used in barcodes , such as GTIN, GLN, SSCC ... Provides parsing of element strings used in GS1 - 128 barcodes .

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accurate in a semantic sense, but dead wrong in a causal sense The popular usage of career criminal is one who chooses a life of crime as an alternative to gainful employment There is an implication of a rough equivalency, at least in terms of continuing means of economic sustenance Gottfredson and Hirschi would probably agree that a career criminal is one who has committed (or at least been arrested for) a large number of crimes They would, however, argue that in purely economic terms the career criminal could make more money bagging groceries on a consistent basis In their theory, the low-self-control crime is impulsive and almost always petty, at least in terms of economic benefit 5 Consistent with their view that these criminal acts are simple or easy, Gottfredson and Hirschi argue that these acts also require little skill or planning.

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Again, this is consistent with their view that those with low self-control are unlikely to acquire substantial academic or vocation skills, since these pursuits run counter to their inherent nature Accordingly, even in criminal acts they are unlikely to choose to commit those that require cognitive or manual skills they have not taken the time, literally, to develop 6 The general theory holds that while crimes often involve pain, loss, or discomfort to the victim(s), this fact is of little consequence to the perpetrator(s) driven by the confluence of opportunity for immediate gratification and low self-control These perpetrators, in Gottfredson and Hirschi s view, are far too self-centered and indifferent to attend to the needs of others or, probably, to even recognize that they exist But, they caution, this does not mean that those motivated by low levels of self-control are necessarily sadists or pathological in their dealings with others.

Kids BURGERS/SALADS/SANDWICHES This burger-and-salad joint is near the Atlantis s beach, catering to the bathing-suit and flip-flops crowd, most often families. To reach the restaurant, you pass beneath a simulated rock-sided tunnel illuminated with flaming torches. The selection of ice cream will cool you off in the midafternoon sun.

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